1. The Mayor (Season 3)

When the Mayor teamed up with Faith, great things happened. By "great," I mean the destruction of a high school and a ruined graduation — but that’s beside the point. The Mayor was so funny and polite, even when killing people. The added detail of him being a germaphobe delivered a level of hilarity that could only come from Joss Whedon. Plus, he was the most fun to watch.

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