2. Bucky Barnes in ‘The Winter Soldier’ (2014)

Cap’s past returns to haunt (and punch) him in the form of the Winter Soldier, a brainwashed HYDRA assassin. The stakes are personal for Cap when he uncovers the man trying to kill him is his former best friend, one of the many casualties of a war Cap never finished fighting. Saving Bucky’s soul almost cost Cap his life — a sacrifice that seemed worth it given that "Winter Soldier" invested more emotional stakes in this villain than audiences are used to seeing from MCU blockbusters. 

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